METHODOLOGY FOR STORAGE TANK N2 INERTIZATION

1.   Objective

To achieve and maintain inert atmosphere using nitrogen (N2) inertization in the storage tank, ensuring safe storage conditions and preventing the risk of combustion or oxidation of stored materials.

2.   Guidelines Used

·      API 2000 Venting Atmospheric and Low-Pressure Storage Tanks

·      NFPA 69

3.   Definitions

·      Normal Venting: The venting required because of operational requirements or atmospheric changes.

·      Nm3/h: Normal cubic meters of air or gas per hour at a temperature of 0°C and pressure of 1.014 bar.

·      Thermal inbreathing: The movement of air or blanketing gas into a tank when vapors in the tank contract or condense as a result of weather changes conditions (e.g., a decrease in atmospheric temperature).

4.   N2 Inertization

·     N2 Inertization concept

The volume of nitrogen gas required to inertize the tank during its operation depends on the volume of inbreathing gas while the liquid is moved out of the tank and the vapours condense or contracts in tank due to atmospheric temperature changes. N2 inertization of tanks is done to provide inert atmosphere in storage tanks storing flammable, combustible or reactive liquids. The volume of N2 required under normal operating conditions is almost equal to the volumetric rate of liquid discharge from the tank. However, due to sudden atmospheric changes and temperature drops the vapour present in storage tanks contracts and condense leading to vacuum and more Nitrogen requirement to fill up the vacuum space generated. This factor is covered under thermal breathing requirements of tank. As per API, calculations for thermal breathing requirements is based on temperature drop of 37.8 °C within 1 hour.

·      N2 Inertization Process

As per API 2000: Venting Atmospheric and Low-Pressure Storage Tanks, design of nitrogen inertization system depends on the total normal inbreathing capacity which is the sum of the inbreathing requirements for liquid movement and thermal effect. During inbreathing nitrogen is provided instead of air to achieve an inert atmosphere withing the storage tank. The Nitrogen supply line is connected to the Storage Tank via Breather valve. As the liquid in the tank is pumped out or drained or due to contraction or condensation of vapours inn storage tanks, vacuum will be created which will trigger breather valve to open and let nitrogen gas to occupy the vacuum space. The tank will be maintained at atmospheric pressure with help of breather valve opening to provide nitrogen to protect the tank against any vacuum while maintaining inert conditions.  

·      Process Calculation for N2 Inertization

The following sequence of activities is implemented during the N2 inertization calculation for inbreathing of storage tanks only.

1.    Calculation of inbreathing requirements is carried out from API 2000 Table 1B—Normal Venting Requirements. And Table 2B —Requirements for Thermal Venting Capacity.

i.        Determine the Flash Point or Boiling Point of Liquid that is stored in the Storage Tank. If both the flash point and boiling points are known then use flash point. On the basis of flash point of liquid that is stored in tank choose an appropriate factor under liquid movement out under inbreathing as per Table-1B.

ii.        Determine pump flowrate responsible for Liquid Movement Out of Tank. The multiplication of factor chosen in step (i) and pump flow rate shall give the Inbreathing requirement for Liquid Movement Out of tank.

Example calculation:

·      Flash Point of Liquid Stored In tank = 9.7 °C.

·      Inbreathing Requirement per m³/hr of Liquid Flow = 0.94 Nm³/hr

·      Amount of Liquid Flow = 5 m³/hr

·      Inbreathing Requirement for Liquid Flow of 5m³/hr = 0.94*5 Nm³/hr = 4.7 Nm³/hr.

i.        Thermal Inbreathing requirements are based on Tank Capacity. Determine Tank Capacity and its Inbreathing requirement as per column 2a, Table-2B 

ii.        For Intermediate values of tank capacity, use interpolation method to find Inbreathing requirement.
Example calculation:

·      Tank with capacity of 25kl = 25m³.

·      25m³ according to table is more than 20m³ and less than 100m³.

·      Unit Inbreathing requirement between 20m³ and 100m³ is (16.9-3.37)/(100-20)=0.169125

·      Inbreathing requirement for 5m³ = (0.169125*5) = 0.845625

·      Inbreathing Requirement for 25m³ (20m³+5m³) = (3.37+0.845) = 4.215625 Nm³/hr

2.    The inbreathing volume due to normal breathing requirements will give volume of nitrogen required when liquid is pumped out of the tank and thermal breathing requirements will give volume of nitrogen required due to temperature changes.

3.    Under normal operating conditions nitrogen requirement will be calculated as in Step 1, Normal Inbreathing requirement due to liquid movement out and Summation of both the inbreathing requirements that is normal and thermal to get maximum inbreathing volume of Nitrogen which may arise if temperature drops by 37.8 °C within 1 hour during liquid outflow from the tank.

4.1.         Data Requirement

Ø Equipment P&IDs

Ø Equipment Specification sheet

Ø Pump Details like Head, Flow rate

Ø MSDS of Chemicals

Ø Nitrogen upstream Details and Nitrogen Purity Level

4.2.         Project Deliverables

Table 1: N2 Inertization Study

4.3 Site Visit Details Format 

4.4 Vent Sizing Calculation Worksheet Format

4.5  Software Used

The N2 Inertization calculation is done using Microsoft Excel.